上海浦东新区高一上学期期末化学试卷含解析

2015-2016302601.A.NaClB.MgCbC.KC1D.CaCl22.（mol）（）A.B.C.D.3.A.B.C.D.4.201512121=1,21A.B.C.D.5.C12（）（）A.CaCbB.CaCIO2C.CaOH2D.CaCO36.A.B.C.D.7.A.aB.C.D.[H8.PPA.32B.15C.PPD.159A.KB.LC.MD.N10.A.B.C.D.11.A.B.C.D.12.A.SiO2B.CO2C.CuD・KOH13.A.B.C.D.14.A.B.C.D.15.C12C12H2OHC1OA.B.C.D.16.A.B.C.D.17.2BF+C12T2CB2,（）A.B.C.D.18.A.CbB.Na2CO3H*C.KIHC10D.AgNChC19.A.B.C.D.20.A.B.C.D.21.A.B.C.D.22.12.01,12.01A.B.C.C・12D.C・1223.A.B.C.D.24.A.①B.②C.③D.④25.88gCO2A.3NAB.NAC.2.0molD.11.2L26.2Fe+3CS2FeCb，28gFe71gC12A.FeC12B.99gFeCl3C.9.33gFeD.17.75gCl227.NAImolNaOHA.NAOHB.3NAC.2NAD.IONA28.xA.ENaOHB.EH2OC.FH2C12D.FNaCl29.25°C,lOlkPaT,0.1molC2H2CO2H2O(I)129.96kJA.2C2H2(g)+5O2(g)T4CO2(g)+2H2O(1)+129.96kJB.2C2H2(g)+502(g)T4CO2(g)+2H2O(g)-259.92kJC.2C2H2(g)+502(g)T4CO2(g)+2H2O(1)-1299.6kJD.2C2H2(g)+5O2(g)T4CO2(g)+2H2O(1)+2599.2kJ30.2H2(g)+O2(g)920(1)+571.6kJ,C3H8(g)+5O2(g)T3CO2(g)+4H2O(1)+2220.0kJ.C3H8lOmol,7694kJ,H2C3H8A.1：1B.2：1C.3：1D.4：14031（1）;O;H°S（2）32.（1）___________________（2）_________________________________（3）_____________________________________a.b.c.d.33.3CI2+8NH3TN2+6NH4CL（1）（2）（3）___________________________________________________________________33.6LC12NH3mol.（）4N?HC1.NH4C1HC1C12NH334.HC11A（2）BHC1B（3）____________________________________________DCD（4）_________________________________________（5）HC1lOOg26.74%HC1L.（6）A,35.I'C12CC14（1）____________________________（2）___________________________________________________H2O2H2O2（3）2（4）____________________________（5）_______________________________________________________________2015-2016302601.A.NaClB.MgCbC.KC1D.CaCbA.2.（mol））A.B.C.D.kg,g,mol,A.AB.gkg,BC.CD.（mol）,DD.3.A.B.C.D.B.4.20151212H,21A.B.C.D.21C.5.Cb（）（）A.CaCbB.CaCIO2C.CaOH2D.CaCO3（）（）（）2Cl2+2CaOH2=CaCIO2+CaCl2+2H2O,CaCIO22Cl2+2Ca(OH)2=Ca(CIO)2+CaCl2+2H2OCa(CIO)B.6.A.B.C.D.A.B.C.D.A.AB.BC.CD.DA.7.A.aB.C.D.[HA.a4,AB.1,BC.1,CD.[H1,DA.8.PP15lbA.32B.15C.PPD.15A.15,AB.32,BC.32PC1515D.P15,15,32,32-15=17,DC.9.A.KB.LC・MD.NKLMNOPQ.ND.10.A.B.C.D.IA（HIIAVIAVIIAA.HC1H-C1AB.C-HBC.H・OCD.DD.11.A.B.C.D.ZA.AB.BC.NaClCD.DB.12.A.SiO2B.CO2C.CuD.KOHA.SiO2AB.CO?CO?BC.CuCD.KOHDB.13.A.B.C.D.A.AB.ABC.CD.DD.14.A.B.C.D.HC1OB.2AgI2Ag+bBC.AgB2Ag+Bi>cD.HC1O2HC1O2HC1+O2DA.AA.15.C12C12000A.B.C.D.HC1HC1O,HC1OC.16.A.B.C.D.，HCl+NaOH=NaCl+H2OHCl+NaOH=NaCl+H2O,C.17.2Br+Cl2^2Cl+Br2,A.B.C.D.A.AB.BC.CD.DD.18.A.CbB.Na2CO3H*C.KIHC10D.AgNO3CC12+H2O^HC1+HC1O,HC1AgClHC1OC12+H2O^HC1+HCIO,A.AB.BC.KIC12，CD.AgClcr,DC・19.A.B.C.D.rhB.A.B.C.D.AABBCCDDA.21.A.B.C.D.A.AB.BC.NaClCD.DB.22.12.01,12.01A.B.C.C・12D.C・12C・121/1212.01A.23.A.B.C.D.vvV＞vA.AB.BC.CD.DB.24.A.①B.②C.③D.④rhB.25.88gCO2A.3NAB・NAC・2.0molD・11.2LVm=22.4L/mol,n=—=—=—CO2MVm%388gCO2—=2mol,NA=2molxNAmol2NA，M6NA，Vm=22.4L/mol,V=2molx22.4L/mol=44.8L,C.26.2Fe+3Cb2FeC13，28gFe702A.FeCbB.99gFeCl3C.9.33gFeD.17.75gCb28gFe71gCh2Fe+3Cb2FeCbn(Fe)=——~0.5mol,n(CI2)=——lmol,5inol_1<2,CbFeCbxmol,Chmol,2Fe+3Cl2A2FeCl32320.5xyx=0.75,y=0.5,（）FeCl30.5molxl62.5g/mol81.25g,Cb1-0.75molx71g/mol=17.75g,D.27.NA1molNaOHA.NAOKB.3NAC.2NAD.IONANaOHAlmolNaOHlmollmolNAABlmolNaOHlmollmol2mol2NABC>lmol3mol3NACD.lmolIONAlmolIONA20NADA.28.xA.ENaOHB.EH2OC.FH?CbD.FNaCl2+FeFe-2e=Fe,2H2O-2e=H2^+2OH',Fe2Cf-2e=Cl2t2H2O-2e=H2/r+2OH',2NaCl+2H2---------=C12+H2+2NaOH.A.2H2O-2e=H2+2OH4mol4molNaOH,ENaOHAB.2H2O-2e'=H2+2OH',4mol4mol,E0B-C.Fe2C1-2e'=Cl2^,2H2O・2e/S，=H21+2OH,4mol2molH2CbFCbCD.Fe2NaCl+2H2O-----------CI2T+H2+2NaOH,4mol4molNaClDD.，29.25°C,lOlkPaT0.1molC2H2A.2CH+2HO(1)+129.96kJ22(Q+5O2T4CO22B.+2HO(g)-259.92kJ2C2H2(£)+5O2T4CO22C.2CH+2HO(1)-1299.6kJ22(g)+5O2T4CO22D.+2H2O(1)+2599.2kJ2C2H2(g)+502T4CO20.1molC2H2CO2CO2H2O(I)129.96kJ0(1)129.96kJ2mol129.96kJx2idq1=2599.2kJ,0.1molC2H2CO2H2O(I)129.96kJ2mol129=2599.2kJ,2C2H2(g)+5O2(g)T4CO2(g)+2H2O(1)+2599.2kJ,D.30.(2H2(g)+O2(g)T2H2O1)+571.6kJ,C3H8(g)+5O2(g)T3CO2(g)+4H2O(I)+2220.0kJ.C3H8lOmol,7694kJ,H2C3H8A.1：1B.2：1C.3：1D.4：1C3H8H2nmol,C3H81Omol-n,n,C3H810mol-n,285.8kJ/molxn+2220.0kJ/molx(lOmol-n)=7694kJn=7.5mol,C3H8lOmol-7.5mol=2.5mol,C3H87.5mol：2.5mol3：1,C.4031.(1)Mg?H2SH-S■■■（2）N[：0]NaCNa*+ClAg++CAgC2.（1）M12,10,6H2S2H?S（2）（1）M12,10,•♦•（）•6OH2S2H2SH-S-H,77♦11•H-S-H；■■■（2）NNaCl=Nf+CAg++Cr=AgCl^,••■[...];NaCl=Na++Cl_Ag++Cl'=AgCl&.32.（1）（2）（3）ca.b.c.d.ZnCuZnZn-2e_=Zn2+,Ftl（1）（2）（3）c.33.3CI2+8NH3TN2+6NH4CI・1C1NH.（2）（3）33.6LC12NH31mol.（4）N2HC1.NH4CIHC1NH33：5・8NH.3+3C12—6NH4CI+N2,NC16“，（1）NN2C1CbCl；NH3;（2）N30,C1012molNH36e・3Cl+8NH=6NHCkN23426mol,3Cl+8NH=6NHCkN22346（）33molCl22molNH333.6LC121.5mol,NH3X2mol=lmol,1;（4）3C12+5NH3N2+3NH4C1+3HC1,C12NH33：5,3：5.34.HC1CD（1）ANaCl+H?SC>4NnHSOg+HCl（2）BHC1BABBDE（3）D（4）（5）HC1100g26.74%HC122.4L.（6）A,（1）HC1（2）AHCIHC1,HC1HC1,（2）（4）HC1（5）HC1HC1VwVmHC1（6）（1）HC1，NaCl+H2SO4NnHSCU+HClT；NaCl+H2SO4NaHSCU+HClT（2）AHC1HC1,HC1HC1,ACBDE,ACBDE；（3）D（4）HC1（5）HC1mg,=26.74%,m=36.5,HC1=lmol,HC1lmolx22.4L/mol=22.4L,22.4L；（6）A,35.C12CC14（1）（2）H2O2）H2O?+2NaI+H2SO$TNa?SQ4+2H?O+l2H2O?+2HIT2H?O+Ig_H2O2j（3）12（4）（5）（1）（2）H2O2（3）（4）（5）（1）（2）H2O2,H2O2+2NaI+H2SO4TN“2SO4+2H2O+l2H2O2+2HIT2H2O+I2），）；H2O2+2NaI+H2SO4^Na2SO4+2H2O+l2H2O2+2HIT2H2O+I2（3）（4）（5）