无铅锡丝MSDS

Safety Data Sheet according to (EC) No 1907/2006 Page 1 of 7 sds no. : 210766 V002.1 Revision: 04.08.2011 printing date: 13.12.2011 97SC C811 5C 0.56MM 0.5KG SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: 97SC C811 5C 0.56MM 0.5KG Relevant identified uses of the substance or mixture and uses advised against: Intended use: Solder Wire Details of the supplier of the safety data sheet: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: +44 1606 593933 Fax-no.: +44 1606 863762 ua-productsafety.uk@uk.henkel.com Emergency Telephone Number: 24 Hours Emergency Tel: +44 (0)1442 278497 SECTION 2: Hazards identification Classification of the substance or mixture: Classification (DPD): Substances and preparations marketed in a specific form or within specific containers need not to be classified in accordance with 67/548/EEC and 1999/45/EC for chemical substances and preparations. Label elements (DPD): Avoid breathing fumes given out during soldering. Flux fumes may irritate the nose, throat and lungs and may after prolonged/repeated exposure give an allergic reaction (asthma). After handling solder wash hands with soap and water before eating, drinking or smoking. Substances and preparations marketed in a specific form or within specific containers need not to be classified in accordance with 67/548/EEC and 1999/45/EC for chemical substances and preparations. Keep out of reach of children. Other hazards: Flux fumes emitted during reflow will irritate the nose and throat and may cause an asthmatic type reaction. This product contains modified rosin. SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: No data available. MSDS-No.: 210766 V002.1 97SC C811 5C 0.56MM 0.5KG Page 2 of 7 Declaration of ingredients according to DPD (EC) No 1999/45: Hazardous components CAS-No. EC Number REACH-Reg No. content Classification Tin 7440-31-5 231-141-8 80 - 100 % Silver 7440-22-4 231-131-3 1 - 5 % Copper Metal 7440-50-8 231-159-6 0,1 - 1 % For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. SECTION 4: First aid measures Description of first aid measures: Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Flush eyes with plenty of water for at least 5 minutes. If irritation persists seek medical attention. Ingestion: Do not induce vomiting. Seek medical advice. Most important symptoms and effects, both acute and delayed: No particular measures required. Indication of any immediate medical attention and special treatment needed: See section: Description of first aid measures SECTION 5: Firefighting measures Combustion behaviour: The product itself does not burn. Any fire extinguishing action should be appropriate to the surroundings. Extinguishing media: Extinguishing media which must not be used for safety reasons: Do not use water on fires where molten metal is present. Special hazards arising from the substance or mixture: High temperatures may produce heavy metal dust, fumes or vapours. The flux medium will give rise to irritating fumes. Advice for firefighters: Wear self-contained breathing apparatus. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. MSDS-No.: 210766 V002.1 97SC C811 5C 0.56MM 0.5KG Page 3 of 7 Environmental precautions: Do not empty into drains / surface water / ground water. Methods and material for containment and cleaning up: Scrape up spilled material and place in a closed container for disposal. Reference to other sections: See advice in chapter 8 SECTION 7: Handling and storage Precautions for safe handling: Extraction is necessary to remove fumes evolved during reflow. When using do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. See advice in chapter 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Conditions for safe storage, including any incompatibilities: Ensure good ventilation/extraction. Store in a cool, dry place. Specific end use(s): Solder Wire SECTION 8: Exposure controls/personal protection Control parameters: Valid for Great Britain Ingredient ppm mg/m3 Type Category Remarks TIN (INORGANIC COMPOUNDS AS SN) 7440-31-5 2 Time Weighted Average (TWA): Indicative ECTLV SILVER (METALLIC) 7440-22-4 0,1 Time Weighted Average (TWA): EH40 WEL SILVER, METALLIC 7440-22-4 0,1 Time Weighted Average (TWA): Indicative ECTLV Colophony (Rosin) and derivatives: Rosin-based flux fume as total resin acids. Exposure controls: Engineering controls: Extraction is necessary to remove fumes evolved during reflow. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. The use of chemical resistant gloves such as Nitrile are recommended. MSDS-No.: 210766 V002.1 97SC C811 5C 0.56MM 0.5KG Page 4 of 7 Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance solid grey Odor None pH not applicable Initial boiling point Not determined Flash point None Decomposition temperature No data available / Not applicable Vapour pressure not applicable Density (25 °C (77 °F)) 7,5 g/cm3 Bulk density No data available / Not applicable Viscosity No data available / Not applicable Viscosity (kinematic) No data available / Not applicable Explosive properties No data available / Not applicable Solubility (qualitative) (Solvent: Water) Insoluble Solidification temperature No data available / Not applicable Melting point 217 °C (422.6 °F) Flammability No data available / Not applicable Auto-ignition temperature No data available / Not applicable Explosive limits No data available / Not applicable Partition coefficient: n-octanol/water Not applicable Evaporation rate No data available / Not applicable Vapor density No data available / Not applicable Oxidising properties No data available / Not applicable Other information: No data available / Not applicable SECTION 10: Stability and reactivity Reactivity: Solder alloy will react with concentrated nitric acid to produce toxic fumes of nitrogen oxides. Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: See section reactivity Conditions to avoid: No decomposition if stored and applied as directed. Incompatible materials: None if used properly. Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. MSDS-No.: 210766 V002.1 97SC C811 5C 0.56MM 0.5KG Page 5 of 7 SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: This material is considered to have low toxicity if swallowed. Inhalative toxicity: Fumes evolved at soldering temperatures will irritate the nose, throat and lungs. Prolonged or repeated exposure to flux fumes may result in sensitisation in sensitive workers. Dermal toxicity: This product is considered to have low dermal toxicity. Skin irritation: Fumes emitted during soldering may irritate the skin. Eye irritation: Fumes emitted during soldering may irritate the eyes. Acute toxicity: Hazardous components CAS-No. Value type Value Route of application Exposure time Species Method Silver 7440-22-4 LD50 > 2.000 mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Skin corrosion/irritation: Hazardous components CAS-No. Result Exposure time Species Method Silver 7440-22-4 slightly irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Copper Metal 7440-50-8 irritating Serious eye damage/irritation: Hazardous components CAS-No. Result Exposure time Species Method Silver 7440-22-4 not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Copper Metal 7440-50-8 not irritating SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Ecotoxicity: May cause long-term adverse effects in the aquatic environment. Mobility: The product is insoluble and sinks in water. Persistence and Biodegradability: The product is not biodegradable. Bioaccumulative potential: Octanol/Water distribution coefficient: Not applicable MSDS-No.: 210766 V002.1 97SC C811 5C 0.56MM 0.5KG Page 6 of 7 Toxicity: Hazardous components CAS-No. Value type Value Acute Toxicity Study Exposure time Species Method Copper Metal 7440-50-8 LC50 > 10 mg/l Fish 96 h Lepomis macrochirus OECD Guideline 203 (Fish, Acute Toxicity Test) SECTION 13: Disposal considerations Waste treatment methods: Product disposal: Wherever possible unwanted solder alloy should be recycled for recovery of metal. Otherwise dispose of in accordance with local and national regulations. Disposal of uncleaned packages: Dispose of in authorised landfill site or incinerate. Waste code 06 04 05 - wastes containing other heavy metals SECTION 14: Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: VOC content < 5,0 % National regulations/information (Great Britain): Remarks The Health & Safety at Work Act 1974. The Control of Substances Hazardous to Health Regulations. L5:General Approved Code of Practice to the COSHH Regulations. HS(G)97:A Step by Step Guide to the COSHH Regulations. HS(G)193:COSHH essentials: Easy steps to control chemicals. IND (G)248L:Solder fume and you. IND(G)249L:Controlling health risks from rosin (colophony) based solder fluxes. MSDS-No.: 210766 V002.1 97SC C811 5C 0.56MM 0.5KG Page 7 of 7 SECTION 16: Other information Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC. Substances and preparations marketed in a specific form or within specific containers need not to be classified in accordance with 67/548/EEC and 1999/45/EC for chemical substances and preparations.