[中学]有机化学 高等学校教材 孔祥文 化学工业出版社 第3章习
题
快递公司问题件快递公司问题件货款处理关于圆的周长面积重点题型关于解方程组的题及答案关于南海问题
和解答
第三章 不饱和烃
1. (1)2-乙基己烯 (2)5-甲基-2-己炔 (3)3-己烯-1-炔 (4)5-乙烯基-2-辛烯-6炔
(5)2-甲基-2,4-己二烯 (6)(E)-2-氟-3-氯-2-戊烯 (7)1-乙基-2-炔丙基环己烯
(8)2,4-己二烯 (9)1,6-二甲基环己烯 (10)顺,反-2,4-己二烯(2Z,4E)2,4-
己二烯
2. (1)B ; CH2=CHCH2CH=CH2 A; BrCH2-BrCH-CH2C?CH
OHCHOOC
OHCCHOHOOCCOOH
OO(2) B; A:
HCCCCH22H
BrCHBr3(3) B;
CH3HCCCCH32HHCCCCH23H
CHBr3BrA; ,
HHCCCHCCCCH3C3HHHH
BrBr(4) ,
O(5) (6) CF3-CH2CH2-Cl (7) (8)(CH3)C=O, CH3COOH
OH
Br
HO(9) (CH3)C=O, HCHO (10) (11)
CHOOCHCOOH23
CHOOCHCOOH23(12) C2H5C?CCN (13) (14)
(15)Br-CH2-CH=CH-CH=CH-CH2Br
CH3(CH2)5CH=CH2KMnO4Ag(NH3)2NO3
CH(CH)CCH325
CH(CH)CCCH32434. (1)
KMnO4
(2)
O
O
Br2/CCl4Ag(NH3)2NO3O(3)
O
CH3(CH2)5CH=CH2O
KMnO4Cu(NH3)2ClCH(CH)CCH325O
CH(CH)CCCH3243
(4)
NaCNAg(NH3)2NO3++(5)
5. (1)C>B>A (2) A; π-π, σ-π B; σ-π, p-π, σ-p C; σ-π, p-π D; σ-p
(3) D>A>C>B (4) E>A>D>F>C>B (5)B>A>C>D (6) B>C>A>D (6)B>C>A>D (7)炔>烯>烷
OO
6. (1) A; B,C ;
(2) A; CH3CH2C?CH B; CH3C?CCH3 (3) A; B;
OCOOHCOOH
C,D; E;
O
O(4) A; B; C; O
(5)
7.
(1)
HBrH2CH3CH2BrCCHHHCCH22
CHCHCCCHCHNa3223NaCCNaHCCH
H2HCHCCHCH3223
P-2cat
(2)
Br2KOHH2SO4BrOH
Br
BrHBrHCl
ClCl (3)
H2CuCl-NH4ClHCCCCHHCCHHCCCCH222HHP-2catH
(4)
HBrH2CH3CH2BrCCHHHCCH22H2HCCCHCNa32HHCCNaHCCH
H2HCCCHH2OC33
HgSO4-H2SO4O
(5)
CHBr2H2CCHCNaHCCNaHCCH
B2H6HH22CCCHOH2O2-OH-
(6)
ClCl2CHClCHClCl22Cl2hr
Cl(7)
HCCCCH22CNHH
HCNCCHCNHHCCH2 (8)
ClCl2CHClCHCCH22NaCCHhr
HgSO4
H2SO4O (9)
O2BrOHCCHOBr2CHO
Br (10)
ClCl2CHCl2hrHCuCl-NH4ClH2CCCHHCCHHCCHHCCC222HP-2catH
CHClCHCCH2HCCNa2H2
8. (1) CH3CH2CH=CH2 (2) (3)
9.
10.
11.炔与Cu(NH3)2Cl沉淀除去。
BrOH
BrOHOHBr12. (1)(2) (3) (4)
Br
(5)
13. (1)B>A (2)A>B (3) A>B>C (4)B>A (5) C>A>B (6)B>A
CH3
H2HHCCCHHCCHCC333314. (1) (2)
CHCH33
HCCCCH33H(3) (4)