JACS PbBOI im

Pb2B5O9I: An Iodide Borate with Strong Second Harmonic Generation Yi-Zhi Huang,† Li-Ming Wu,† Xin-Tao Wu,† Long-Hua Li,† Ling Chen,*,† and Yong-Fan Zhang*,‡ Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, and Department of Chemistry, Fuzhou UniVersity, Fuzhou, Fujian 350002, P. R. China Received July 8, 2010; E-mail: chenl@fjirsm.ac.cn Abstract: The combination of lone-pair effects on Pb2+ cations and the smaller electronegativity of I- anions into the pentaborate framework generates a phase-matchable material, Pb2B5O9I, with the largest powder SHG response among borates, about 13.5 times that of KDP (KH2PO4), and transparency over the near-UV to middle-IR region. DFT calculations on electronic structure and cutoff-energy-dependent SHG coefficients confirm these origins. Borates have long been a remarkable source of nonlinear optical (NLO) materials,1 and some examples, such as �-BaB2O4 (BBO) and LiB3O5 (LBO), have been commercially manufactured and used worldwide. The asymmetric electronic distributions on the distorted planar anions of [B3O6]3- and [B3O7]5- are responsible for the large second harmonic generation (SHG) in these, respectively. The design and construction of new inorganic NLO materials often utilize MOn polyhedra as effective noncentrosymmetric (NCS) building units. These may contain second-order Jahn-Teller (SOJT) distorted cations such as d0 transition metal ions,2,3 p-cations with stereochemically active lone pairs (quoted as lone-pair effects subsequently),4-7 or d10 cations with large polar displacement in a few cases.8,9 The combination of diverse functional building units can produce materials with high NLO performance; for example, powdered Cd4BiO(BO3)3 shows an SHG response about six times that of KH2PO4 (6× KDP), representing the largest powder NLO coefficient among borates to date.8 In such a compound, the combinations of the polar displacement of d10 Cd2+ ion, lone-pair effects on Bi3+, and π-delocalization of BO3 are believed to be the origin of the strong SHG activity. In this communication, we report the discovery of Pb2B5O9I, a phase-matchable iodide borate with an SHG intensity measured on ground crystals approximately 13.5 times that of KDP and about twice as large as that of Cd4BiO(BO3)3.8 Although lighter halide pentaborates M2B5O9X (M ) Ca, Sr, Ba, Pb, Eu; X ) Cl, Br) are known, the iodide, Pb2B5O9I, has not been obtained because of synthetic difficulties.10-12 The sharp increase of the SHG activity along isostructural Ca < Sr < Ba < Pb for M and Cl < Br for X suggested that the key SHG factors come from not only the lone pairs on Pb2+ but also the bonding of the halogen anions. Consequently, the unknown iodide pentaborate, Pb2B5O9I, would be expected to exhibit the strongest SHG activity among M2B5O9X. In contrast, the theoretical calculations of SHG coefficients utilizing Phillips-Van Vechten-Levine-Xue bond theory indicated that the planar BO3 triangle is the sole functional group affecting the NLO properties of the chloride and bromide pentaborates.10 Here, we report the synthesis of Pb2B5O9I and density functional theory (DFT) calculations that indicate that its remarkably large SHG intensity arises from all three components, the I- anion, the lone 6s2 pair on Pb2+, and the borate groups. The prismatic colorless or pale yellow Pb2B5O9I crystals (Figure S1) together with a second phase, brown lamellar PbB4O7 (ICSD 203201) were synthesized in a solid-state reaction of PbI2/PbO/ B2O3 in an evacuated silica tube (Supporting Information). The purity of the handpicked Pb2B5O9I crystals was confirmed by the XRD pattern (Figure S2a). The isostructural Pb2B5O9I also crystal- lizes in space group Pnn2 (No. 34). The three-dimensional network was built from [B5O93-]n and [Pb2O9I15-]n substructures shown in Figure 1. The primary building units in the [B5O93-]n substructure (Figure 1a) are BO4 tetrahedra and BO3 triangles connected in a double six-member ring motif (Figure S3a). Here the BO4 tetrahedra form chains along the c axis via vertex sharing, which are further linked along both a (via B2O3) and b axes (via B1O3) so as to define large channels along the c axis. The centers of such channels are occupied by I1 or I2 anions. The [Pb2O9I15-]n substructure is made of knitted chains of PbO7I2 monocapped hexagonal bipyramids via sharing I apexes along a and b axes, respectively (Figures 1b, S3b-c). The Pb1- and Pb2-polyhedron strings are condensed via shared I1-O8-O3 and I2-O4-O5 faces and I1-O7 edges (Figure S4). Compared with the earlier Pb2B5O9X (X ) Cl, Br), the PbO7I2 polyhedra exhibit significantly greater distortions, such as the angle reduction for I-Pb-I (137° and 152°) with respect to Cl-Pb-Cl (157° and 163°) and Br-Pb-Br (150° and 160°) as well as the larger Pb1-O distance ranges (2.50-3.28 Å vs 2.50-2.92 Å for Cl and 2.48-3.02 Å for Br, respectively). The structure parameters indicate an enhancement of the SOJT distortion in PbO7I2 † Chinese Academy of Sciences. ‡ Fuzhou University. Figure 1. (a) Crystal structure of Pb2B5O9I viewed down c axis with Pb-O and Pb-I bonds omitted for clarity. Gray: BO4 tetrahedra; black: BO3 triangles. (b) [Pb2O9I15-]n substructure along c axis. Gray and black: PbO7I2 monocapped hexagonal bipyramids. Table 1. Optical Properties for Pb2B5O9X (X ) I, Br, Cl) experimental calculated X SHGintensitya transparent region (µm) band gap energy (eV)b SHG coefficients (pm/V)c I 13.5, PM 0.40-6.96 3.33/3.36 16.6/9.4/1.8 Br 4.7, PM 0.38-6.86 3.54/3.54 7.4/2.6/-1.2 Cl 0.7, PM 0.31-6.80 3.72/3.69 4.5/1.0/-1.8 a Relative to KDP (150-210 µm) with λincident ) 1064 nm. PM ) phase-matchable (Figure S5). b Direct/indirect gaps. c Static d15/d24/d33 (d15 ) d31, d24 ) d32) according to the length-gauge formalism.13,14 10.1021/ja106066k  XXXX American Chemical Society J. AM. CHEM. SOC. XXXX, xxx, 000 9 A winy 高亮 winy 高亮 winy 高亮 winy 高亮 winy 高亮 winy 打字机 winy 打字机 winy 打字机 polyhedra, which arises from the larger electronegativity difference between the coordinated I- and O2- anions. The measured and calculated optical parameters for Pb2B5O9X (X ) I, Br, Cl) are summarized in Table 1 (more details in the Supporting Information). Powdered Pb2B5O9I shows an SHG activity of approximately 13.5 × KDP, much greater than those of the two lighter analogues (Figure S5), a relative smaller band gap of about 3.1 eV (Figure S6a), and a similar infrared absorption edge of about 7.0 µm (Figure S6b). From Cl to I, the increasing SHG and the decreasing band gap are consistent with the calculated results. An additional calculation also indicates that the strong SHG intensity of Pb2B5O9I does not originate from just a reduction of the band gap. If Pb2B5O9I had a band gap of 3.7 eV, i.e., the calculated value for Pb2B5O9Cl, the calculated d15 would decrease only to 11.1 pm/V, still significantly greater than the 4.5 pm/V for Pb2B5O9Cl. Subsequently, the detailed electronic structures around the Fermi level (EF) were also studied. The densities of states (DOS) of Pb2B5O9I are shown in Figure 2a with assigned numbers to mark different regions in the valence bands (VB) and conduction bands (CB) for the sake of clarity. Below EF, the B-O bonding states are dispersed from VB-5 to VB-2, and Pb 6s states mix with I 5p as well as O 2p over VB-4 to VB-1. Above EF, the prominent characters for each region are as follows: CB-1, Pb 6p states (with small contribution of I 5p); CB-2, B-O π-antibonding states on BO3; CB-3, I 5d states; and CB-4, B-O σ-antibonding states from both BO3 triangles and BO4 tetrahedra (with small I 5d contribution). The lone pairs on Pb2+ are characterized mainly by Pb 6s-O 2p bonding interactions at VB-4 and (Pb 6s-O 2p)-I 5p antibonding-antibonding interactions at VB-1. The high-energy VB-1 region dominated by I 5p states is responsible for the lone-pair effects on Pb2+, which is visualized by the asymmetric electron distribution around the cations as shown in Figure 2b (versus the symmetric density at VB-4, Figure S7). This lone-pair effect is different from that for MOx polyhedra (M ) p metals) in which M ns usually mixes with O 2p and M np.15-18 Obviously, the filled I 5p in Pb2B5O9I better matches the Pb 6s energy than does the empty Pb 6p. Furthermore, relative to Pb2B5O9Cl and Pb2B5O9Br (Figure S8), the I 5p in Pb2B5O9I contributes more significantly to the lone-pair effects on Pb2+ at VB-1 owing to the smaller electronegativity of I, and I 5d states disperse much more around the empty B-O states, in both CB-3 and CB-4, because of their strong penetration effect. Note that, from I to Cl, the B-O states in the electronic structures of Pb2B5O9X do not show obvious changes. The local structure contributions of Pb2B5O9I to the overall SHG efficiency have been estimated by the cutoff-energy-dependent SHG coefficient according to the length-gauge formalism.13,14 As clearly shown in Figure 2c, the states at VB-1, CB-3, and CB-4 make the most significant contributions to the SHG coefficient. Similar calculations for Pb2B5O9Br and Pb2B5O9Cl (Figure S9) show that these regions contribute much less to the overall SHG efficiencies. Since the dominant characters of VB-1, CB-3, and CB-4 regions are filled I 5p, empty I 5d, and B-O states, respectively, one may speculate that the electronic transitions from I 5p to I 5d and to B-O states are reflected in the high SHG efficiency. However, the following evidence excludes such a speculation. A hypothetical “Ba2B5O9I” without lone pairs has been built in the same crystal- lographic structure of Pb2B5O9I. The parallel calculations on “Ba2B5O9I” generate a very small coefficient, 3.2 pm/V, which is even smaller than 4.5 pm/V for Pb2B5O9Cl. Obviously, the main contributor in VB states should come from the lone-pair effect on Pb2+ at VB-1 instead of I 5p alone. Consequently, the sharp SHG increase for Pb2B5O9I in comparison with Pb2B5O9Br and Pb2B5O9Cl originates mainly with the increased cooperation of I-, Pb2+ lone pairs and B-O groups. In summary, a new phase-matchable compound Pb2B5O9I with the largest powder SHG coefficient among borates has been synthesized and characterized. Theoretical analyses reveal that the cooperation of I-, lone pairs on Pb2+, and the BO3 and BO4 groups are responsible for the remarkable SHG response. The growth of large crystals for further physical property studies is ongoing. Acknowledgment. This research was supported by the National Natural Science Foundation of China under Projects (90922021, 90922022, 20773130, 20733003, 20821061, 20973175, 20773024), the “Knowledge Innovation Program of the Chinese Academy of Sciences” (KJCX2-YW-H20), and New Century Excellent Talents at Universities of Fujian Province (HX2006-97). 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(b) Asymmetric electron distribution (>0.06 eV/Å3) around Pb2+ at VB-1 region. (c) The cutoff- energy-dependent static SHG coefficients for Pb2B5O9I, dashed line: EF; dotted line: different regions in VB and CB. B J. AM. CHEM. SOC. 9 VOL. xxx, NO. xx, XXXX C O M M U N I C A T I O N S winy 高亮 winy 高亮 winy 高亮 winy 高亮 winy 高亮 winy 高亮 winy 高亮 winy Highlight