变压器油MSDS

材料 关于××同志的政审材料调查表环保先进个人材料国家普通话测试材料农民专业合作社注销四查四问剖析材料 安全数据 表 关于同志近三年现实表现材料材料类招标技术评分表图表与交易pdf视力表打印pdf用图表说话 pdf MATERIAL SAFETY DATA SHEET 1．产品与公司标识 Product and Company Identification 产品名称 Product Name 变压器油基础油 Transformer oil base stock(TOBS) 产品类型 Product Type 润滑油基础油 lubricant oil base stock 生 产 商Manufacturer 中国石油克拉玛依石化公司 petrochina karamay petrochemical comoany 中国新疆克拉玛依市，PC:834003， JinLong zhen，Karamay city， XinJiang P.R.China 电话 Telephone No +86-0990-6993617 传真 Fax +86-0990-6992118 2．组成/成分Composition/Information of Ingredients 化学名称Chemical Name CAS-No. EC号 Weight-%重量百分比 轻质环烷基馏分油Distillates (petroleum), clay-treated light naphthenic 64742-45-6 265-147-7 100% 3．危险性标识Hazards identification危险说明 在正常使用的情况下，本产品不存在不可预计的危险。This product does not have any unexpected hazards in proper use. 物理和化学危险 Physical and Chemical Hazard 温度升高超过物理性质的指标时，会释放出可燃的蒸气和分解产物。 At elevated temperature over the limitation of physical property, flammable vapor or decomposition product may released. 人类健康 Human health 吸入蒸气或烟雾（在高温情况下才会产生）会刺激呼吸道。长期或 重复皮肤接触会造成脱脂或刺激。眼睛接触可能引起刺激。Inhalation of vapors and/or mists(Generate at high temperature only) might irritate respiratory tract.Prolonged or repeated skin contact will cause defatting and possible irritation.Eye contact might cause irritation. 环境 Environment 矿物白油缓慢生物降解，产品将在环境中保留一段时间。存在污染 地面、土壤和水的风险。This product is slow biodegradation, and will remain for a period of time in the environment. Risk existed for contamination of earth, soil and water. 第 1 页 共 6 页 4．急救 措施 《全国民用建筑工程设计技术措施》规划•建筑•景观全国民用建筑工程设计技术措施》规划•建筑•景观软件质量保证措施下载工地伤害及预防措施下载关于贯彻落实的具体措施 First Aid Measures 一般忠告General advice: 遵照优良的工业卫生和安全惯例处理Handle in accordance with good industrial hygiene and safety practice. 吸入 Inhalation 如果吸入雾、烟或蒸气引起刺激反应，立即转移到新鲜空气处。如果呼吸 困难可进行吸氧。如症状未缓解，请与医生联系。如呼吸停止应进行人工 呼吸并立即送医院就诊。If inhalation of mists, fumes or vapors causing irritation, move victim to fresh air, provide oxygen if breathing is difficult. If the symptoms persist, get medical advice. Carry out artificial respiration if breathing stops, and send to medical service immediately 皮肤接触 Skin Contact 立即脱去被污染的衣物，擦去矿物油，并用香皂和大量水清洗。衣物未清 洗前勿使用。如果发生刺激反应，请与医生联系。Remove immediately contaminated clothing, wipe away the oil and wash with soap and plenty of water. Do not reuse the contaminated clothing until cleaned. If irritation occurs, obtain medical advice. 眼睛接触 Eye Contact 用大量的水清洗。如果发生刺激反应，请与医生联系。Rinse with plenty of clean water. If irritation or redness occurs, obtain medical advice. 吞服 Ingestion 用水清洗口腔。如果吞下量较大请与医生联系。不要进行催吐。Clean mouth with water. Obtain medical advice if a large amount has been swallowed. Do not induce vomiting. 5．救火措施 Fire-fighting Measures 合适的灭火剂 Extinguishing Media 使用干粉、二氧化碳或泡沫灭火剂。也可使用喷雾或水雾。Extinguish with dry chemical, carbon dioxide (CO2) or foam. Water mist or spray may be used. 不 能 使 用 的 灭 火 剂 Unsuitable Extinguishing Media 不要直接使用水流。Do not use a direct stream of water. 消防人员防护 Protection of firefighter 消防人员应穿着全身防护服，并配带正压呼吸器。The firefighters should cover overall protective clothing and equipped with positive pressure breathing apparatus. 6．意外泄露控制措施Accidental Release Measures 个 人 措 施 Personal Precaution 佩带适当的防护设备。立即熄灭火源。Wear suitable protective equipment and clothing. Eliminate any resource of ignition. 环境措施 Environmental Precautions: 防止溢出物进入或蔓延到排水沟、水道和土壤中。与当地环境保护部门 联系。Prevent spill to enter and spread to drain, water resource and soil. Contact local environment protection authorities. 清 洁 方 法 Cleaning Method 如果无危险，应尽快停止泄漏。少量泄漏使，用粘土、沙、土或其它合 适的材料吸收。大量泄漏时，用泵将泄漏的油泵入合适的容器中，然后 再用上面提到的材料吸收。正确的废气方法按第 13 部分。If without danger, eliminate leaking source as quick as possible. In case of small 第 2 页 共 6 页 spills, absorb with clay, sand, earth or other suitable material. In large spills, pump the oil into a suitable container then absorb with material mentioned above. Proper disposal method please see paragraph 13. 7．操作和储存Handling and Storage 处理 Handling 避免热、明火和强氧化剂。所有处理设备要进行接地，以防电火花。如 果处于高温下或高速运动的机械设备中，可能会释放出蒸气或雾，因此 需要良好的通风，使用防爆通风设备。Avoid heat, open flames and strong oxidizing agents. Ground all handling equipment to prevent sparking. If handled at elevated temperatures or with high speed mechanical equipment, vapors or mists might be released and require a well ventilated workplace. Should applied explosion-proof ventilation equipments. 贮存 Storage 贮存于干燥，凉爽环境下，通风良好处。避免强烈日光，明火和高温。 Store in a dry and cool condition and a well ventilated place. Keep away from strong sunlight, open flames and high temperatures. 8．暴露控制/个体保护Exposure Controls/Personal Protection 控制因素Control Parameter 如果存在矿物油的尘雾，应进行通风。Apply ventilation if exist the mist of mineral oils, 个 人 防 护 Personal Protection •呼吸防护 Respiratory protection: • 手 的 防 护 Hand protection: • 眼 睛 防 护 Eye protection: •皮肤与身体防护 Skin and body protection: 如果产品需要加热，应佩戴能防护有机物蒸气的面具或呼吸器。If the product needs to be heated, use organic steam proof mask or breathing apparatus. In an exhaust and ventilation condition, no protection mask is normally required. 如果存在与皮肤反复接触的可能性，佩带防油手套。Wear suitable oil-resistant protective gloves if there is a risk of repeated skin contact. 如果可能发生溅出，佩带护目镜。Wear safety goggles / safe shield if splashes may occur. 如果可能存在皮肤身体接触，穿戴防护服，经常更换或污染时更换。 Wear protective clothing if there is a risk of skin contact and change them frequently, or when contaminated. 卫 生 措 施 Hygienic Measures: 在吃饭、喝水、吸烟，使用化妆品和上厕所前用肥皂和水洗手。受污 染的衣物在重新使用前要清洗。Wash hand with soap and water before eating, drinking, smoking，cosmetic make-up or using toilet. Wash contaminated clothing before reuse. 9．物理和化学性质Physical and Chemical Properties 性状 Form 浅色液体 pale Liquid 颜色 Color <1.0 气味 Odor 无味 Odorless 第 3 页 共 6 页 倾点 Pour Point <-35℃ 初馏点 Initial Boiling Point >250℃ 密度 Density at 20℃ 882 kg/m3 闪点 Flash Point, COC, >140℃ 自燃点 Auto ignition temp: >270°C 水中溶解性 Solubility in water 不溶 Non Soluble 有机溶剂中溶解性 Solubility in Organic Solvent 可溶 Soluble 粘度 Kinematic Viscosity at 40℃ <13mm2/s 碳型分析 Carbon Type Analysis CA，% <10 CN，% >40 PCA 含量 DMSO extractible compounds according to IP346 <3% 10．稳定性和反应活性Stability and Reactivity 稳定性 Stability： 在通常环境下稳定。Stable at normal conditions. 避免 Avoid: 过热或强氧化剂。Excessive heating and highly oxidizing agents. 分 解 产 物 的 危 险 性 Hazardous Decomposition Products： 热解或分解产物很大程度上取决于条件。会形成一氧化碳、二氧 化碳和未知有机物。Pyrolysis or combustion products are largely depend on condition. Carbon Monoxide, Carbon Dioxide and other unidentified organic compounds may be formed. 11．毒性资料Toxicological Information 急 性 毒 性 试 验 Acute toxicity: 现有研究表明 LD50 口服>5000g/kg，可以认为急性毒性较低。Studies available indicate that oral LD50>5000 mg/kg which is considered as low acute toxicity. There no expected negative effects to environment. 吸入 Inhalation: 无数据。但长时间和重复吸入高温下产生的蒸气或雾可能会刺激呼吸 道。No data available. But prolonged and repeated inhalation of mist of vapor generated at elevated temperatures may irritate respiratory tract. 食入 Ingestion: 无数据。但可能导致恶心甚至呕吐和腹泻。No data available. But may cause nausea and eventually vomiting and diarrhoea. 皮肤接触 Skin contact: 无数据。但长时间和重复性接触可能导致皮肤脱脂并引发刺激反应。 No data available. But prolonged or repeated exposure may lead to defatting of the skin and subsequent irritation. 眼睛接触 Eye contact: 无数据。但可能会引起发红和短暂疼痛。No data available. But may cause redness and transient pain. 致敏 Sensitization: 研究表明无致敏迹象。Studies indicate no evidence of sensitization. 12．生态资料Ecological Information 概述Acute toxicity: 根据 OECD-203实验方法进行检测，各产品鱼类急性毒性检测结果 第 4 页 共 6 页 均显示 LC50>100mg/L，属于低毒类物质。对环境无可预见的损害。 Test according OECD-203, the testing results of series product show that acute toxicity to fish is >100mg/L which is considered as low acute toxicity. 迁移率Mobility: 低，因为不溶于水。Low, due to low water solubility. 持 续 性 / 降 解 能 力 Persistence/degradability 根据 OECD-301D 方法进行检测，各产品 28 天生物降解率介于 10.1%~27.1%间。物质不符合可迅速生物降解的 标准 excel标准偏差excel标准偏差函数exl标准差函数国标检验抽样标准表免费下载红头文件格式标准下载 。Test according to OECD-301D, in 28d bio-degradation, the degradability of series products are between 10.1% and 27.1%.. Substances may not meet criteria for ready biodegradability. 生 物 积 聚 Bio-accumulation: 无数据，但烃类分子的体积降低了生物积聚的可能性。No data available. The size of the hydrocarbon molecules reduces the risk for bioaccumulation. 13．废弃物处置 Disposal Consideration 一般认为，未使用的产品可以不视为有害废弃物，被污染的包装物应视为有害废弃物，按当地法规 进行处置。本产品的用户有责任在废弃时确定材料是否符合废弃物的标准，并建立适用的废弃程序。 In general consideration, residue of unused products is not regarded as hazardous waste. Contaminated package should be regarded as dangerous waste. Dispose the residue of products/packing in accordance with local regulations. The user of material has the responsibility to determine at the time of disposal, whether the material meets the criteria of hazardous waste, and establish suitable disposal process. 14．运输信息 Transportation Information 根据中国和国际相应的法规，产品在陆路、铁路运输、海运和空运时不作为有危险的商品。（ADR, RID, IMDG, IATA-DGR）The product is not classified as hazardous goods for land, railway, sea and air transport according to the Chinese and other international regulations (ADR, RID, IMDG, IATA-DGR). 15．法规信息 Regulatory Information 根据中国和欧洲危险物质和制品分类原则，不视为危险品。不需要法定标识。Classify according to European directives on classification of hazardous substances and preparations, not classified as hazardous. No statutory label required. 本材料所有组分在IECSC/EINECS/TSCA化学品目录上都有列出。All components of this material are listed on the IECSC/EINECS/TSCA Inventory of Chemical Substances. 16．其它信息 Other Information 本安全数据表上所列信息基于目前现有数据，根据我们所掌握的知识据信是正确的。给定的信 息用作安全地处理、使用、加工、贮存、运输、废弃和排放时的指南，不作为产品质量规格的 保证。信息只与指定材料相关。 The information provided in this Safety Data Sheet is base on the 第 5 页 共 6 页 第 6 页 共 6 页 data available at present, and is believed to be correct to the best of our knowledge. The information given is designed as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated. 要了解其它资料，请与我公司联系。For further information, please contact with our company. Product Data Sheet of Transformer Oil 项 目 Test Items 分析方法 Test Method 质量指标 Specification 牌号 25 45 密度 Density at 20 kg/m℃ 3 GB/T1884 895 max. 895 max. 运动粘度 Kinematic Viscosity, mm2/s GB/T265 at 40℃ 13 Max. 11 Max. at -10℃ 200 Max. / at -30℃ / 1800 Max. 倾点 Pour Point，℃ GB/T3535 -22 Max. / 凝点 Solidification Point，℃ GB/T510 / -45 Max. 苯胺点， ℃ 报告 Report 闪点 Flash Point，℃ GB/T261 140 Min. 135 Min. 酸值 Acid Number，mgKOH/g GB/T264 0.03 Max. 击穿电压（间距2.5mm）Breakdown Voltage，KV GB/T507 35 Min. 介质损耗因数 Dissipation Factor ，（90℃） GB/T5654 0.005 Max. 界面张力 Interfacial Tension，mN/m GB/T6541 40 Min. 38 Min. 水份Water Content， mg/kg SH/T0207 报告 Report 水溶性酸碱 Soluble Acid or Alkali，% GB/T259 无 ND 腐蚀性硫 Corrosive Sulphur SH/T0304 非腐蚀性 No Corrosive 氧化安定性 Oxidation Stability SH/T0206 氧化后酸值 Acid Number，mgKOH/g 0.2 Max. 氧化后沉淀 Sludge,% 0.05 Max. 发布日期 Issued date:：2007年 08月 07日